Hamiltonian Thermodynamics on Symplectic Manifolds
Authors
Abstract
We describe a symplectic approach towards thermodynamics in which thermodynamic transformations are described by (symplectic) Hamiltonian dynamics. Upon identifying the spaces of equilibrium states with Lagrangian submanifolds of a symplectic manifold, we present a Hamiltonian description of thermodynamic processes where the space of equilibrium states of a system in a certain ensemble is contained in the level set on which the Hamiltonian assumes a constant value. In particular, we work out two explicit examples involving the ideal gas and then describe a Hamiltonian approach towards constructing maps between related thermodynamic systems, e.g., the ideal (non-interacting) gas and interacting gases. Finally, we extend the theory of symplectic Hamiltonian dynamics to describe (a) the free expansion of the ideal gas which involves irreversible generation of entropy, and (b) a symplectic port-Hamiltonian framework for the ideal gas which is exemplified through two problems, namely, the problem of isothermal expansion against a piston and that of heat transfer between a heat bath and the gas via a thermal conductor.
Keywords
hamiltonian systems, symplectic geometry, thermodynamics
Citation
- Journal: International Journal of Theoretical Physics
- Year: 2026
- Volume: 65
- Issue: 5
- Pages:
- Publisher: Springer Science and Business Media LLC
- DOI: 10.1007/s10773-026-06301-9
BibTeX
@article{Ghosh_2026,
title={{Hamiltonian Thermodynamics on Symplectic Manifolds}},
volume={65},
ISSN={1572-9575},
DOI={10.1007/s10773-026-06301-9},
number={5},
journal={International Journal of Theoretical Physics},
publisher={Springer Science and Business Media LLC},
author={Ghosh, Aritra and Harikumar, E.},
year={2026}
}References
- MrugaŁa R (1978) Geometrical formulation of equilibrium phenomenological thermodynamics. Reports on Mathematical Physics 14(3):419–427. https://doi.org/10.1016/0034-4877(78)90010- – 10.1016/0034-4877(78)90010-1
- Peterson MA (1979) Analogy between thermodynamics and mechanics. American Journal of Physics 47(6):488–490. https://doi.org/10.1119/1.1178 – 10.1119/1.11788
- Vojta G (1990) Symplectic Formalism for the Thermodynamics of Irreversible Processes. Annalen der Physik 502(2–3):251–258. https://doi.org/10.1002/andp.1990502022 – 10.1002/andp.19905020222
- Mrugala R, Nulton JD, Schön JC, Salamon P (1990) Statistical approach to the geometric structure of thermodynamics. Phys Rev A 41(6):3156–3160. https://doi.org/10.1103/physreva.41.315 – 10.1103/physreva.41.3156
- Mrugała R (1993) Continuous contact transformations in thermodynamics. Reports on Mathematical Physics 33(1–2):149–154. https://doi.org/10.1016/0034-4877(93)90050- – 10.1016/0034-4877(93)90050-o
- Balian R, Valentin P (2001) Hamiltonian structure of thermodynamics with gauge. Eur Phys J B 21(2):269–282. https://doi.org/10.1007/s10051017020 – 10.1007/s100510170202
- Mrugała R (2005) Structure groupU(n) × 1 in thermodynamics. J Phys A: Math Gen 38(50):10905–10916. https://doi.org/10.1088/0305-4470/38/50/00 – 10.1088/0305-4470/38/50/003
- Rajeev SG (2008) A Hamilton–Jacobi formalism for thermodynamics. Annals of Physics 323(9):2265–2285. https://doi.org/10.1016/j.aop.2007.12.00 – 10.1016/j.aop.2007.12.007
- Grmela M (2014) Contact Geometry of Mesoscopic Thermodynamics and Dynamics. Entropy 16(3):1652–1686. https://doi.org/10.3390/e1603165 – 10.3390/e16031652
- Bravetti A, Nettel F (2014) Thermodynamic curvature and ensemble nonequivalence. Phys Rev D 90(4). https://doi.org/10.1103/physrevd.90.04406 – 10.1103/physrevd.90.044064
- Bravetti A, Lopez-Monsalvo CS (2015) Para-Sasakian geometry in thermodynamic fluctuation theory. J Phys A: Math Theor 48(12):125206. https://doi.org/10.1088/1751-8113/48/12/12520 – 10.1088/1751-8113/48/12/125206
- Bravetti A, Lopez-Monsalvo CS, Nettel F (2015) Contact symmetries and Hamiltonian thermodynamics. Annals of Physics 361:377–400. https://doi.org/10.1016/j.aop.2015.07.01 – 10.1016/j.aop.2015.07.010
- Baldiotti MC, Fresneda R, Molina C (2016) A Hamiltonian approach to Thermodynamics. Annals of Physics 373:245–256. https://doi.org/10.1016/j.aop.2016.07.00 – 10.1016/j.aop.2016.07.004
- Cvetič M, Gibbons GW, Lü H, Pope CN (2018) Killing horizons: Negative temperatures and entropy super-additivity. Phys Rev D 98(10). https://doi.org/10.1103/physrevd.98.10601 – 10.1103/physrevd.98.106015
- Alarcón D, Fernández de Córdoba P, Isidro JM, Orea C (2018) On the van der Waals Gas, Contact Geometry and the Toda Chain. Entropy 20(8):554. https://doi.org/10.3390/e2008055 – 10.3390/e20080554
- Van der Schaft A, Maschke B (2018) Geometry of Thermodynamic Processes. Entropy 20(12):925. https://doi.org/10.3390/e2012092 – 10.3390/e20120925
- Bravetti A (2019) Contact geometry and thermodynamics. Int J Geom Methods Mod Phys 16(supp01):1940003. https://doi.org/10.1142/s021988781940003 – 10.1142/s0219887819400036
- Ghosh A, Bhamidipati C (2019) Contact geometry and thermodynamics of black holes in AdS spacetimes. Phys Rev D 100(12). https://doi.org/10.1103/physrevd.100.12602 – 10.1103/physrevd.100.126020
- Simoes AA, de León M, Valcázar ML, de Diego DM (2020) Contact geometry for simple thermodynamical systems with friction. Proc R Soc A 476(2241). https://doi.org/10.1098/rspa.2020.024 – 10.1098/rspa.2020.0244
- van der Schaft A (2021) Liouville geometry of classical thermodynamics. Journal of Geometry and Physics 170:104365. https://doi.org/10.1016/j.geomphys.2021.10436 – 10.1016/j.geomphys.2021.104365
- Ghosh A, Bandyopadhyay M, Bhamidipati C (2022) Contact geometry and quantum thermodynamics of nanoscale steady states. Physica A: Statistical Mechanics and its Applications 585:126402. https://doi.org/10.1016/j.physa.2021.12640 – 10.1016/j.physa.2021.126402
- Aragón-Muñoz L, Quevedo H (2022) Symplectic structure of equilibrium thermodynamics. Int J Geom Methods Mod Phys 19(11). https://doi.org/10.1142/s021988782250178 – 10.1142/s021988782250178x
- Ghosh A (2023) Hamilton–Jacobi approach to thermodynamic transformations. Pramana - J Phys 97(1). https://doi.org/10.1007/s12043-023-02523- – 10.1007/s12043-023-02523-2
- Cariñena JF, Choudhury AG, Guha P (2024) Levinson–Smith Dissipative Equations and Geometry of GENERIC Formalism and Contact Hamiltonian Mechanics. J Nonlinear Sci 34(6). https://doi.org/10.1007/s00332-024-10090- – 10.1007/s00332-024-10090-y
- Arnold VI (1989) Mathematical Methods of Classical Mechanics. Springer New Yor – 10.1007/978-1-4757-2063-1
- van der Schaft A, Jeltsema D (2014) Port-Hamiltonian Systems Theory: An Introductory Overvie – 10.1561/9781601987877
- Duindam V, Macchelli A, Stramigioli S, Bruyninckx H (2009) Modeling and Control of Complex Physical Systems. Springer Berlin Heidelber – 10.1007/978-3-642-03196-0
- Eberard D, Maschke BM, van der Schaft AJ (2007) An extension of Hamiltonian systems to the thermodynamic phase space: Towards a geometry of nonreversible processes. Reports on Mathematical Physics 60(2):175–198. https://doi.org/10.1016/s0034-4877(07)00024- – 10.1016/s0034-4877(07)00024-9
- Ramirez H, Le Gorrec Y (2022) An Overview on Irreversible Port-Hamiltonian Systems. Entropy 24(10):1478. https://doi.org/10.3390/e2410147 – 10.3390/e24101478
- Schroeder DV, Gould H (2000) An Introduction to Thermal Physics. Physics Today 53(8):44–45. https://doi.org/10.1063/1.240569 – 10.1063/1.2405696
- Corless RM, Gonnet GH, Hare DEG, Jeffrey DJ, Knuth DE (1996) On the LambertW function. Adv Comput Math 5(1):329–359. https://doi.org/10.1007/bf0212475 – 10.1007/bf02124750