On the Port-Hamiltonian Models of some Electrochemical Processes

Authors

Daniel Sbarbaro

Abstract

Electrochemical processes play an important role in many natural and technological processes; such as, mineral refining, water purification, energy storage and generation. The port-Hamiltonian framework has been widely used for modeling and control design of mechanical and electro-mechanical systems. It has demonstrated to be an important tool to analyze and integrate models of different domains. This work discusses the modeling of isothermal electrochemical processes as port-Hamiltonian systems. Port-Hamiltonian models based on the Gibbs energy function are derived for two examples. They illustrate the main steps to obtain a port-Hamiltonian representation from molar and charge balance equations. Further work will consider non isothermal reactions and the analysis of system considering also diffusion phenomena.

Keywords

Electrochemical reactions; port Hamiltonian; Modeling

Citation

• Journal: IFAC-PapersOnLine
• Year: 2018
• Volume: 51
• Issue: 3
• Pages: 38–43
• Publisher: Elsevier BV
• DOI: 10.1016/j.ifacol.2018.06.010
• Note: 6th IFAC Workshop on Lagrangian and Hamiltonian Methods for Nonlinear Control LHMNC 2018

BibTeX

@article{Sbarbaro_2018,
  title={{On the Port-Hamiltonian Models of some Electrochemical Processes}},
  volume={51},
  ISSN={2405-8963},
  DOI={10.1016/j.ifacol.2018.06.010},
  number={3},
  journal={IFAC-PapersOnLine},
  publisher={Elsevier BV},
  author={Sbarbaro, Daniel},
  year={2018},
  pages={38--43}
}

Download the bib file

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